✦ LIBER ✦

Kinetics and mechanism of the addition of allyl magnesium bromide to the double bond of cinnamyl alcohol. Catalysis by magnesium bromide.

✍ Scribed by Hugh Felkin; Christian Kaeseberg

Publisher: Elsevier Science
Year: 1970
Tongue: French
Weight: 207 KB
Volume: 11
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89424-1

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Torsional strain involving partial bonds

Torsional strain involving partial bonds. The steric course of the reaction between allyl magnesium bromide and 4-t-butyl-cyclohexanone

✍ Marc Chérest; Hugh Felkin 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 269 KB

The influence of steric and torsional st

The influence of steric and torsional strain on the steric course of additions to cyclohexanones. The reaction between 4-T-butylcyclohexanone and T-butylallyl magnesium bromide.

✍ Marc Chérest; Hugh Felkin 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 204 KB

The steric outcome of the reactions of simple cyclohexanones (e.g., 1) vith hydrides and Grignard reagents is governed by the relative magnitudes of the strains in the transition states At and E', leading to the axial ,2& and equatorial ZE alcohols respectively.le2 t BB" 'a 1 . 24

Prostaglandins and congeners II. The con

Prostaglandins and congeners II. The conjugate addition of 3-t-butoxyoctyl magnesium bromide to cyclopentenones. A synthesis of rac. 11-deoxy-13-dihydroprostaglandin-E1.

✍ Robert E. Schaub; Martin J. Weiss 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 112 KB

Nucleophilic addition to C,Cdouble bonds

Nucleophilic addition to C,Cdouble bonds. Part IX. Kinetics and mechanism of the base-catalyzed intramolecular cyclization of olefinic alcohols

✍ Gerardo M. Ramos Tombo; Camille Ganter 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 German ⚖ 600 KB

## 4, ' ) ' ) For solvent isotope effects in acid/base equilibria, see [lo]. For structural reasons, through-space interactions are negligible in such compounds. A steric effect was not detected by X-ray analysis. The interaction diagram was constructed according to the usual theoretical consider

ChemInform Abstract: Asymmetric Synthesi

ChemInform Abstract: Asymmetric Synthesis of 1,2-Diamines by the Addition of Allylic Zinc and Magnesium Reagents to N,N′-Bis[(S)-1-phenylethyl]ethanediimine.

✍ Giuseppe Alvaro; Fabrizia Grepioni; Stefano Grilli; Lucia Maini; Gianluca Martel 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 2 views

Nucleophilic Addition to C,C-Double Bond

Nucleophilic Addition to C,C-Double Bonds. Part VIII. The standard enthalpies of formation of anti9,10-10endo-hydroxytricyclo [4.2.1.12,5]deca-3,7-dien-9-one and 9-Oxatetracyclo [5.4.0.03,10.04,8]undec-5-en-2-one and kinetic data for the cyclization of the olefinic alcohol to the ether

✍ Alan A. Smeaton; William V. Steele; Gerardo M. Ramos Tombo; Camille Ganter 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 258 KB 👁 2 views

## Abstract In view of the significance of steric compression in the base‐catalyzed intramolecular cyclization of polycyclic olefinic alcohols, the standard enthalpies of formation of __anti__^9,10^‐10 __endo__‐hydroxytricyclo [4.2.1.1^2,5^]deca‐3,7‐dien‐9‐one **(1)** and 9‐oxatetracyclo [5.4.0.0^3