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Nucleophilic addition to C,Cdouble bonds. Part IX. Kinetics and mechanism of the base-catalyzed intramolecular cyclization of olefinic alcohols

✍ Scribed by Gerardo M. Ramos Tombo; Camille Ganter

Publisher: John Wiley and Sons
Year: 1985
Tongue: German
Weight: 600 KB
Volume: 68
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19850680817

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✦ Synopsis

4, ' ) ' )

For solvent isotope effects in acid/base equilibria, see [lo].

For structural reasons, through-space interactions are negligible in such compounds. A steric effect was not detected by X-ray analysis. The interaction diagram was constructed according to the usual theoretical considerations [14] [15]. These results were also confirmed quantitatively by MIND0/3 calculations [16] [17].

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