Relationship Between Retention and Homologous Factor of Homologues in RPLC
β Scribed by F.A. Wang; J.C. Song; Y.H. Wang; Y. Zhao; T.Z. Cao
- Book ID
- 102616260
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 216 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0026-265X
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β¦ Synopsis
Based on Jiang MingQian's organic compound homologous linear rule, a quantitative relationship between retention and the homologous factor is identified for homologous in reversed-phase highperformance liquid chromatography and is supported by experimental and citation data. Calculated and compared with experimental data, the overall average relative derivation for 267 data sets is (3.77 %) for 18 groups of homologues in five kinds of mobile phases on five kinds of columns. 1995 Academic Press. Inc.
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The rule of intersection point between retention of homologues and column temperature in reversed-phase liquid chromatography is reported, based on the thermodynamic theory, with the basic equation of the retention in reversed-phase liquid chromatography, proposed by Vigh and others. We have derived
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