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Reinvestigation of the Elementary Chemical Kinetics of the Reaction C 2 H 5• + HBr (HI) → C 2 H 6 + Br • (I • ) in the Range 293–623 K and Its Implication on the Thermochemical Parameters of C 2 H 5• Free Radical

✍ Scribed by Leplat, N.; Wokaun, A.; Rossi, M. J.


Book ID
121433105
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
1020 KB
Volume
117
Category
Article
ISSN
1089-5639

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The gas-phase dehydrogenation of cyclopentene to cyclopentadiene catalyzed by iodine in. the range 178-283'C has been found to obey a rate law consistent with the slow rate-determining step, I + c-C5Hs --t HI + c-C5H, , log [ka/(l moleL1 sec-')I = 10.25 \* 0.08 -(12.26 f 0.18)/0, where 0 = 2.303RT i

Kinetics of the reactions of C2H5, n-C3H
✍ Arkke J. Eskola; Vladimir A. Lozovsky; Raimo S. Timonen 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 187 KB 👁 1 views

## Abstract The kinetics of the C~2~H~5~ + Cl~2~, __n__‐C~3~H~7~ + Cl~2~, and __n__‐C~4~H~9~ + Cl~2~ reactions has been studied at temperatures between 190 and 360 K using laser photolysis/photoionization mass spectrometry. Decays of radical concentrations have been monitored in time‐resolved measu