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Regiospecificity of the 1,4 cycloaddition of 2-methyl-1-penten-3-one to methyl crotonate and to methyl methacrylate

✍ Scribed by Gore, William E.; Pearce, Glenn T.; Silverstein, Robert M.


Book ID
126254234
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
644 KB
Volume
41
Category
Article
ISSN
0022-3263

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Non-stereospecific 1, 2-photocycloadditi
✍ R.J. Atkins; G.I. Fray; A. Gilbert; M.W. bin Samsudin πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 219 KB

Electron-deficient ethylenes such as maleic anhydride, maleimides, acrylonitrile, and methyl vinyl ketone undergo exclusive 1,2-photocycloaddition to benzene. 1 In all these cases the addition reaction is also stereospecific, giving rise to exo adducts (l), 273 -and it is significant