𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1,3-Cycloaddition of Benzonitrile oxides to diazepines.II. 1-ethoxycarbonyl-4-methyl- and 6-methyl-1,2-diazepine

✍ Scribed by Paolo Beltrame; Enzo Cadoni; Costantino Floris; Gioanna Gelli


Book ID
108371888
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
908 KB
Volume
49
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Asymmetric synthesis of (R)-6-amino-1-me
✍ Shiro Kato; Hiroshi Harada; Toshiya Mode 📂 Article 📅 1997 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 772 KB

## Abstract An efficient asymmetric synthesis of (__R__)‐6‐amino‐1‐methyl‐4‐(3‐rnethylbenzyl)hexahydro‐1__H__‐1,4‐diazepine [(__R__)‐2] which serves as the amine part of (__R__)‐1, a potent and selective 5‐HT~3~ receptor antagonist, is described. Formation of the hexahydro‐1__H__‐1,4‐diazepine ring

6-Ethyl-5,7-di­methyl-6H-1,4-diazepine-2
✍ Nesterov, Volodymyr V. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 217 KB

In the title compound, C 11 H 12 N 4 , the diazepine ring exhibits a boat conformation, where the displacements of the C atoms attached to the nitrile groups and the C atom attached to the ethyl group are 0.591 (1), 0.585 (1) and 0.845 (1) A Ê from the base of the boat.