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Non-stereospecific 1, 2-photocycloaddition of methyl acrylate and methyl methacrylate to benzene

✍ Scribed by R.J. Atkins; G.I. Fray; A. Gilbert; M.W. bin Samsudin


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
219 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis


Electron-deficient ethylenes such as maleic anhydride, maleimides, acrylonitrile, and methyl vinyl ketone undergo exclusive 1,2-photocycloaddition to benzene. 1 In all these cases the addition reaction is also stereospecific, giving rise to exo adducts (l), 273 -and it is significant


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## Abstract The variation of copolymerization rate with composition obtained for the system methyl acrylate (1)/methyl methacrylate (2)/benzene/2,2′‐azoisobutyronitrile using standard techniques of polymerization rate measurements has been interpreted on the basis of a penultimate effect upon the p