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Regioselective reductions of steroidal conjugated dienes by DIBAH

✍ Scribed by Sara Montiel-Smith; Leticia Quintero-Cortes; Jesús Sandoval-Ramirez

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
166 KB
Volume
36
Category
Article
ISSN
0040-4039

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The ruthenium tetroxide oxidation of ste
The ruthenium tetroxide oxidation of steroidal conjugated homoannular dienes
✍ W.J. Rodewald; Z. Bończa-Tomaszewski 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 217 KB

During our investigations on sgntheaie of heterocyolic eteroids the problem of degradation of conjugated homoannular dlenee by oxidatlve cleavage of olefinic bond8 arose. Rutlmenlum tetroxide was found to be a good oxidant for degradation of steroidal oonjugated ketones and aromatic steroids 'e2). T