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Stereoselectivity in the Rhodium-Catalysed Reductions of Non-Conjugated Dienes

✍ Scribed by Bao Nguyen; John M. Brown


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
521 KB
Volume
351
Category
Article
ISSN
1615-4150

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Selective dihydroxylation of non-conjuga
✍ Merritt B. Andrus; Salvatore D. Lepore; Joseph A. Sclafani 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 250 KB

Non-conjugated dienes were dihydroxylated using the commercially available osmium tetroxide AD-mix-a reagent resulting in highly regioselective dihydroxylation of the terminal olefin rather than the internal, more substituted olefin. These findings now allow for the use of allylmetal reagents on sub