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Regioselective 1,3-Dipolar Cycloaddition Reactions of 4-Methylene-2-oxazolidinones with Benzonitrile Oxide

✍ Scribed by Newton, Rebecca; Savage, G. Paul

Book ID: 121698700
Publisher: Commonwealth Scientific and Industrial Research Organisation Publishing
Year: 2008
Tongue: English
Weight: 318 KB
Volume: 61
Category: Article
ISSN: 0004-9425
DOI: 10.1071/ch08111

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ChemInform Abstract: Regioselective 1,3-

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## Abstract Benzonitrile oxide cycloadds to the CC bond of substituted 4,5‐dihydro‐3‐methylene‐2(3__H__)‐furanones 1a–1g. Thus, (__E__)‐1a and (__E__)‐1b are converted into the corresponding isoxazolinespirodihydrofuranones (4__RS__,5__RS__)‐2a and (4__RS__,5__RS__)‐2b, and (__E__)‐1c is converted

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Reactivity of 2-methylene-1,3-dicarbonyl compounds. 1,3-dipolar cycloaddition reaction with nitrile oxide

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## Abstract The reaction of 2‐methylene‐1,3‐dicarbonyl compounds **1** and nitrile oxides, which were prepared from hydroxymoyl chlorides **2** with triethylamine, gave 5,5‐disubstituted 2‐isoxazolines **3** regioselectively.