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Regiochemistry, stereochemistry, and mechanism of addition of trifluoroacetic acid to (Z)-cyclooctene

โœ Scribed by Nordlander, J. Eric; Kotian, Kirtivan D.; Raff, Dwight E.; Njoroge, George F.; Winemiller, Jeffry J.


Book ID
120074442
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
725 KB
Volume
106
Category
Article
ISSN
0002-7863

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Tricyclic oxonium-directed addition: Reg
โœ Eleuterio Alvarez; Eduardo Manta; Julio D Martin; Matias L Rodriguez; Catalina R ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 275 KB

The regio-and stereochemistry of electrophile-promoted transannular ring expansion of cycle 1,5-and 1,6-epoxyalkenes and cycle trans-1,5bisepoxides were studied. The results are rationalized in terms of tricyclic oxonium intermediates showing the directing ability of oxygen substituents in the regio