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Additions and Corrections - Regiochemistry, Stereochemistry, and Mechanism of Addition of Trifluoroacetic Acid to (Z)-Cyclooctene

โœ Scribed by Nordlander, J.; Kotian, Kitivan; Raff, II, Dwight; Njoroge, F.; Winemiller, Jeffry


Book ID
127042992
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
145 KB
Volume
106
Category
Article
ISSN
0002-7863

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Tricyclic oxonium-directed addition: Reg
โœ Eleuterio Alvarez; Eduardo Manta; Julio D Martin; Matias L Rodriguez; Catalina R ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 275 KB

The regio-and stereochemistry of electrophile-promoted transannular ring expansion of cycle 1,5-and 1,6-epoxyalkenes and cycle trans-1,5bisepoxides were studied. The results are rationalized in terms of tricyclic oxonium intermediates showing the directing ability of oxygen substituents in the regio