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Stereochemistry of acyl halide addition to olefins. Intramolecular cyclization of cis-4-cyclooctene-1-carboxylic acid chloride

✍ Scribed by Erman, William F.; Kretschmar, Herbert C.


Book ID
126105940
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
884 KB
Volume
33
Category
Article
ISSN
0022-3263

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and treated with lBuCl (1.18 g, 12.8 mmol) directly after filtration. The mixture was stirred at room temperature for 12 h before the orange solution was evaporated to dryness. Recrystallization of the residue from toluene (ca. 30 mL) affords a yellow crystalline powder (2.50 g, 40%). which decompos