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Regiochemistry of the Cycloaddition of Unsymmetrical Alkenes with an Imino-1,2,4-Dithiazole

✍ Scribed by Mark G. Epstein; Edward J. Valente; Warren J. L. Wood

Book ID
106404797
Publisher
Springer
Year
2011
Tongue
English
Weight
333 KB
Volume
41
Category
Article
ISSN
1572-8854

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Cycloadditionβˆ’Elimination Reactions of 5
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✍ Franz Tittelbach; Siegfried Vieth; Matthias Schneider πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 568 KB

5-Imino-1,2,4-thiadiazolidin-3-ones 1 react with compounds alkylidene-1,2,4-dithiazolidines 12 are formed. The reaction products with enamines undergo hydrolysis and elimination containing electron-rich double bonds such as enamines and ester enolates to afford the 2-iminothiazolidines 3, 4, and 10