Fused thiazolidine 11 and thiazoline derivatives Ha-c are obtained by intramolecular cycloaddition-elimination reactions of appropriately substituted Mninothiatriazolines 10 and Ha-c. The incorporation of a sidechain phenyl group excercises a favorable effect on cycllxation since no reaction is obse
✦ LIBER ✦
Cycloaddition-elimination reactions of 4-methyl-5-(substituted)-imino-Δ2-1,2,3,4-thiatriazolines with isocyanates
✍ Scribed by Gerrit L'abbé; Nancy Weyns; Ingrid Sannen; Pieter Delbeke; Suzanne Toppet
- Book ID
- 112129939
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1991
- Tongue
- English
- Weight
- 350 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-152X
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In recent publications we have discussed the mechanistic aspects of the cycloaddition-elimi-2 nation reactions of 1,2,3,4-thiatriazoline-5-imines 1 with isothiocyanates, isocyanates and electrophilic nitriles. Rased on the knowledge gained from these experiments we expect that the reactions of 1 wit