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[4 + 1] Cycloaddition Reactions of o-Thioquinones with Isocyanides: Novel Syntheses of 2-Imino-1,3-oxathioles.

✍ Scribed by Vijay Nair; Bini Mathew; A. U. Vinod; Joseph Swaroop Mathen; Sindu Ros; Rajeev S. Menon; R. Luxmi Varma; R. Srinivas


Publisher
John Wiley and Sons
Year
2003
Weight
109 KB
Volume
34
Category
Article
ISSN
0931-7597

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Kinetics of the [2+ + 4]-Cycloaddition R
✍ Herbert Mayr; Joachim Henninger πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 287 KB πŸ‘ 1 views

The kinetics of the [2 + + 4] cycloadditions of 1,3-dithian-2-cycloaddition pathway by the correlation lg k = s (E + N). Though a concerted cycloaddition pathway is not excluded ylium ions (1) with 1,3-dienes was investigated photometrically in dichloromethane. The second-order rate by this finding,