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Regio- and stereospecific living polymerization and copolymerization of (E)-1,3-pentadiene with 1,3-butadiene by half-sandwich scandium catalysts

✍ Scribed by Nishii, Kei; Kang, Xiaohui; Nishiura, Masayoshi; Luo, Yi; Hou, Zhaomin


Book ID
120413603
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
447 KB
Volume
42
Category
Article
ISSN
1477-9226

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## Abstract 1,3‐Butadiene, 4‐methyl‐1,3‐pentadiene and styrene were polymerized with dicyclopentadienyltitanium dichloride/methylaluminoxane (Cp~2~TiCl~2~/MAO) and dicyclopentadienyltitanium chloride/MAO (Cp~2~TiCl/MAO). These systems are less active than cyclopentadienyltitanium trichloride/MAO (C