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Regio- and Diastereoselective Stepwise [8 + 3]-Cycloaddition Reaction between Tropone Derivatives and Donor–Acceptor Cyclopropanes

✍ Scribed by Rivero, Alexandra R.; Fernández, Israel; Sierra, Miguel Ángel


Book ID
121190761
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
933 KB
Volume
15
Category
Article
ISSN
1523-7060

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Highly Diastereoselective Synthesis of 1-Pyrrolines via SnCl 4 -Promoted [3 + 2] Cycloaddition Between Activated Donor-Acceptor Cyclopropanes and Nitriles. -The products are isolated as single cis diastereomers. Using standard imine chemistry, the preparation of useful derivatives such as (VI) is p