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Regio- and Chemoselective Transfer Hydrogenation of Quinolines Catalyzed by a Cp*Ir Complex.

✍ Scribed by Ken-ichi Fujita; Chihiro Kitatsuji; Shigetoyo Furukawa; Ryohei Yamaguchi


Publisher
John Wiley and Sons
Year
2004
Weight
146 KB
Volume
35
Category
Article
ISSN
0931-7597

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Fast and Chemoselective Transfer Hydroge
✍ Walter Baratta; Katia Siega; Pierluigi Rigo πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 81 KB πŸ‘ 2 views

## Abstract Aromatic, aliphatic and Ξ±,β‐unsaturated aldehydes are quickly, quantitatively and chemoselectively reduced to primary alcohols with 2‐propanol using 0.05–0.01 mol % of the terdentate CNN ruthenium complex RuCl(CNN)(dppb) (1) [HCNN=6‐(4′‐methylphenyl)‐2‐pyridylmethylamine; dppb=Ph~2~P(CH