Reflected Shock Tube Studies of High-Temperature Rate Constants for OH + CH4 → CH3 + H2O and CH3 + NO2 → CH3O + NO
✍ Scribed by Srinivasan, N. K.; Su, M.-C.; Sutherland, J. W.; Michael, J. V.
- Book ID
- 115449888
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 214 KB
- Volume
- 109
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
## Abstract The Laser Photolysis‐Shock Tube technique coupled with H‐atom atomic resonance absorption spectrometry has been used to study the reaction, H + CH~4~ → CH~3~ + H~2~, over the temperature range, 928–1697 K. Shock‐tube studies on the reverse of this reaction, CH~3~ + H~2~ → H + CH~4~, usi