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Refined Representation of Falloff Curves for the Reaction HO + NO 2 + N 2 → (HONO 2 , HOONO) + N 2

✍ Scribed by Troe, Jürgen

Book ID
127332502
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
382 KB
Volume
116
Category
Article
ISSN
1089-5639

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Application of RRKM theory to the reacti
Application of RRKM theory to the reactions OH + NO2 + N2 → HONO2 + N2 (1) and ClO + NO2 + N2 → ClONO2 + N2 (2); a modified gorin model transition state
✍ G. P. Smith; D. M. Golden 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 647 KB

## Abstract Rate constants as a function of both temperature and pressure were calculated for the title reactions using RRKM theory in conjunction with a modified Gorin transition state. The modification introduces a hindrance parameter which accounts for repulsive interactions between the rotating