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Master Equation Models for the Pressure- and Temperature-Dependent Reactions HO + NO2 → HONO2 and HO + NO2 → HOONO

✍ Scribed by David M. Golden; John R. Barker; Lawrence L. Lohr

Publisher
John Wiley and Sons
Year
2004
Weight
59 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract A theoretical analysis of the temperature and pressure dependence of the reaction HO + NO~2~ + M ⇔︁ HONO~2~ + M is made over the temperature range 50–1400 K and the pressure range 10^−4^–10^3^ bar where experimental data are available. The treatment accounts for contributions from anhar

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## Abstract A temperature and pressure kinetic study for the CH~3~O~2~ + HO~2~ reaction has been performed using the turbulent flow technique with a chemical ionization mass spectrometry detection system. An Arrhenius expression was obtained for the overall rate coefficient of CH~3~O~2~ + HO~2~ rea

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The rate constant for the NH 3 ϩ NO 2 L NH 2 ϩ HONO reaction (1) has been kinetically modeled by using the photometrically measured NO 2 decay rates available in the literature. The rates of NO 2 decay were found to be strongly dependent on reaction (1) and, to a significant extent, on the secondary

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A laser flash photolysis-long path absorption technique has been employed to study the kinetics of the reaction BrO + NO2 + M Q products as a function of temperature (248-346 K), pressure (16-800 torr), and buffer gas identity (N2, CF4). The reaction is found to be in the falloff regime between thir