Reexamination of the structure of MoO(O2)2(H2O)(hmpa), hmpa=hexamethylphosphoramide by crystallographic and theoretical means
β Scribed by Craig A. Bayse; Ampa Jimtaisong; Anil K. Kandalam; Rudy L. Luck; Ravindra Pandey; Mark J. Stevens
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 112 KB
- Volume
- 754
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
Structuresof (HrO), (W20), H+(HaO)zo (HW20) and H+(HrO)rr (HW21) clusters were determined by applyingtheZemer's intermediate neglect of differential overlap self-consistent field unrestricted Hat-tree-Fock (ZINDO SCF UHF) method after appropriate parametrization and yield a dodecahedral arrangement
Spectrophotometric and electrochemical behaviour of V(III) ions was investigated in H,O + DMPU and H,O + HMPA mixed solvents. While optical studies have revealed the resolvation of V(III) already in Hz0 rich solutions, it has been found that the reduction of V(II1) to V(H) at the mercury electrode y
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