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Synthesis and Structure of the Molecular Rectangle [{MoO2(C17H14N2O6)}2]4–

✍ Scribed by Anne-Kathrin Duhme


Publisher
John Wiley and Sons
Year
1998
Tongue
German
Weight
131 KB
Volume
624
Category
Article
ISSN
0372-7874

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Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space