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Reductive sulfenylation. A general method for the .alpha.-sulfenylation of cyclic ketones

โœ Scribed by Gassman, Paul G.; Gilbert, David P.; Cole, Susan M.

Book ID
111688937
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
498 KB
Volume
42
Category
Article
ISSN
0022-3263

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โœ J.S. Yadav; B.V. Subba Reddy; Ruchi Jain; Gakul Baishya ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 153 KB

The sulfenylation of ketones having a-hydrogens has been achieved using N-chlorosuccinimide (NCS) under mild reaction conditions to produce a-ketothioethers in excellent yields with high selectivity. The use of NCS makes this method quite simple, convenient and practical.