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Reductive Elimination of Ether from T-Shaped, Monomeric Arylpalladium Alkoxides

✍ Scribed by James P. Stambuli; Zhiqiang Weng; Christopher D. Incarvito; John F. Hartwig

Book ID
101539060
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
135 KB
Volume
119
Category
Article
ISSN
0044-8249

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✍ G. MANN; J. F. HARTWIG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Ir(III). -Based on isolation of the palladium alkoxo complexes (VI) and their thermally-induced decomposition to t-butylbenzene and the biphenyls ( VIII) and (IX) or the ether (IVa) and their reaction with amines giving derivatives like (XI) it is found that Pd-catalyzed amination and etheration of