Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III)

ChemInform Abstract: Palladium Alkoxides

ChemInform Abstract: Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III).

✍ G. MANN; J. F. HARTWIG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Ir(III). -Based on isolation of the palladium alkoxo complexes (VI) and their thermally-induced decomposition to t-butylbenzene and the biphenyls ( VIII) and (IX) or the ether (IVa) and their reaction with amines giving derivatives like (XI) it is found that Pd-catalyzed amination and etheration of