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Reductive desulfurization using the raney nickel — Sodium hypophosphite combination system without racemization of a secondary alcohol

✍ Scribed by Kiyoharu Nishide; Yukihiro Shigeta; Kenichi Obata; Takehisa Inoue; Manabu Node


Book ID
103410104
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
197 KB
Volume
37
Category
Article
ISSN
0040-4039

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A Raney nickel — sodium hypophosphite co
✍ Manabu Node; Kiyoharu Nishide; Yukihiro Shigeta; Kenichi Obata; Hiroaki Shiraki; 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 703 KB

Sulfides and sulfoxides bearing an optically active secondary alcohol wece desul~ with a Rmey nickel (W-2)-sodium hypophosphite combination system to give optically active alcohols in high yields without racemization. However, the combination system was not effective with sulfides whioh comprise m a