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ChemInform Abstract: Reductive Desulfurization Using the Raney-Nickel/Sodium Hypophosphite Combination System without Racemization of a Secondary Alcohol.

✍ Scribed by K. NISHIDE; Y. SHIGETA; K. OBATA; T. INOUE; M. NODE

Book ID
112034274
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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A Raney nickel β€” sodium hypophosphite co
A Raney nickel β€” sodium hypophosphite combination system for reductive desulfurization without racemization of optically active secondary alcohol
✍ Manabu Node; Kiyoharu Nishide; Yukihiro Shigeta; Kenichi Obata; Hiroaki Shiraki; πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 703 KB

Sulfides and sulfoxides bearing an optically active secondary alcohol wece desul~ with a Rmey nickel (W-2)-sodium hypophosphite combination system to give optically active alcohols in high yields without racemization. However, the combination system was not effective with sulfides whioh comprise m a