𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reductive Cleavage of the Te—Te Bond in Diphenyl Ditelluride by the Sm/CrCl3(cat.) System; Preparation of Telluroesters and Unsymmetrical Phenyltellurides

✍ Scribed by Yun-Kui Liu; Yung-Min Zhang

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
308 KB
Volume
20
Category
Article
ISSN
0256-7660

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The reduction of diphenyl ditelluride by the Sm/CrCl~3~ (cat.) system led to a telluride anion. This species reacted with acid chlorides, alkyl halides, and α,β‐unsaturated enoates or α,β‐unsaturated ene nitrites to afford telluroesters and unsymmetrical phenyltellurides, respectively, in moderate to good yields under mild and neutral conditions.

📜 SIMILAR VOLUMES

ChemInform Abstract: Sm/ZrCl4 Induced Re
ChemInform Abstract: Sm/ZrCl4 Induced Reductive Cleavage of Te—Te Bond in Diaryl Ditellurides: A Novel Method for the Synthesis of Unsymmetrical Tellurides.
✍ Songlin Zhang; Yongmin Zhang; Qiaoling Li 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: A New Path for the
ChemInform Abstract: A New Path for the Reductive Cleavage of Te—Te Bond by the System of Cp2TiCl2/i-BuMgBr and Its Utility in Synthesis of Unsymmetrical Tellurides (III).
✍ Xian Huang; Wei-Xin Zheng 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v