๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Reductive cleavage of benzyl ethers with lithium naphthalenide. A convenient method for debenzylation

โœ Scribed by Hsing-Jang Liu; Judy Yip; Kak-Shan Shia

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
222 KB
Volume
38
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

An operationally simple, high-yielding and highly chemoselective procedure has been developed for the conversion of benzyl ethers to the corresponding alcohols, using lithium naphthaknide as the reagent. Q 1997 Elsevier Science Ltd.

๐Ÿ“œ SIMILAR VOLUMES

Reductive cleavage of N,N,Nโ€ฒ,Nโ€ฒ-tetramet
Reductive cleavage of N,N,Nโ€ฒ,Nโ€ฒ-tetramethylphosphorodiamidates with lithium naphthalenide. A convenient procedure for deoxygenation of alcohols
โœ Hsing-Jang Liu; Xiao Shang ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 169 KB

A simple, effective alternative procedure has been developed for the reductive cleavage of the N,N,N',N'-tetramethylphosphorodiamidate group, using lithium naphthalenide as the reagent.

Lithium naphthalenide induced reductive
Lithium naphthalenide induced reductive alkylation of ฮฑ-cyano ketones. A general method for regiocontrol of ฮฑ, ฮฑ-dialkylation of ketones
โœ Hsing-Jang Liu; Jia-Liang Zhu; Kak-Shan Shia ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 188 KB

An efficient general method for the consecutive introduction of two alkyl groups to the ct carbon of a ketone carbonyl has been developed, making use of the lithium naphthalenide induced reductive alkylation of an ~t-cyano ketone system as a key operation.