Reductive cleavage of N,N,N′,N′-tetramethylphosphorodiamidates with lithium naphthalenide. A convenient procedure for deoxygenation of alcohols
✍ Scribed by Hsing-Jang Liu; Xiao Shang
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 169 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A simple, effective alternative procedure has been developed for the reductive cleavage of the N,N,N',N'-tetramethylphosphorodiamidate group, using lithium naphthalenide as the reagent.
📜 SIMILAR VOLUMES
An operationally simple, high-yielding and highly chemoselective procedure has been developed for the conversion of benzyl ethers to the corresponding alcohols, using lithium naphthaknide as the reagent. Q 1997 Elsevier Science Ltd.
## Alcohols, carboxyiic acids and carbonyi compounds give the corresponding alkyl iotiides in mocltratc to good yields on reaction with N,N-diethylanilinc-borane complex and iodine.