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Reductions with Metal Hydrides. XIV. Reduction of 2-Tetrahydropyranyl and 2-Tetrahydrofuranyl Ethers

✍ Scribed by Eliel, Ernest L.; Nowak, Bernard E.; Daignault, Ronald A.; Badding, Victor G.

Book ID
125417951
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
832 KB
Volume
30
Category
Article
ISSN
0022-3263

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✍ David J. Goldsmith; R.C. Joines πŸ“‚ Article πŸ“… 1965 πŸ› Elsevier Science 🌐 French βš– 197 KB

Although the action of metal hydrides on a-haloketones generally leads to halohydrins (1) a number of exceptions have been reported. In these, the debrominated ketone has been obtained instead (2). We wish to report here the results of the hydride reduction of a bromoketone which yields almost exclu