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Reduction of 6-Trichloromethyl-2-pyrones with Metal Hydrides and with Zinc

✍ Scribed by E. Dunkelblum; M. Rey; André S. Dreiding

Book ID
102857554
Publisher
John Wiley and Sons
Year
1971
Tongue
German
Weight
633 KB
Volume
54
Category
Article
ISSN
0018-019X

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Although the action of metal hydrides on a-haloketones generally leads to halohydrins (1) a number of exceptions have been reported. In these, the debrominated ketone has been obtained instead (2). We wish to report here the results of the hydride reduction of a bromoketone which yields almost exclu