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Reductions with Metal Hydrides. XVI. Reduction of Some 2-Tetrahydropyranylamines

โœ Scribed by Eliel, Ernest L.; Daignault, Ronald A.


Book ID
126193318
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
274 KB
Volume
30
Category
Article
ISSN
0022-3263

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The debrominative reduction of 2-bromois
โœ David J. Goldsmith; R.C. Joines ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 197 KB

Although the action of metal hydrides on a-haloketones generally leads to halohydrins (1) a number of exceptions have been reported. In these, the debrominated ketone has been obtained instead (2). We wish to report here the results of the hydride reduction of a bromoketone which yields almost exclu