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Reduction of sulfoxides catalyzed by oxo-complexes

✍ Scribed by Ivânia Cabrita; Sara C.A. Sousa; Ana C. Fernandes

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
235 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

This work reports the catalytic activity of the oxo-complexes HReO 4 , MoO 2 (acac) 2 , WO 2 Cl 2 , and VO(acac) 2 in the reduction of sulfoxides with PhSiH 3 or HBcat. The results obtained showed that the catalyst systems PhSiH 3 /HReO 4 (5 mol %) and HBcat/HReO 4 (5 mol %) are highly efficient for the deoxygenation of sulfoxides. The complex MoO 2 (acac) 2 was also efficient, but the reactions required more time and heating. Finally, the complexes WO 2 Cl 2 and VO(acac) 2 showed a moderate activity.

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