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Reduction of sulfoxides and sulfilimines catalyzed by metalloporphins

✍ Scribed by Toshiyuki Nagata; Toshiaki Yoshimura; Ken Fujimori; Shigeru Oae

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
219 KB
Volume
25
Category
Article
ISSN
0040-4039

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✍ IvΓ’nia Cabrita; Sara C.A. Sousa; Ana C. Fernandes πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 235 KB

This work reports the catalytic activity of the oxo-complexes HReO 4 , MoO 2 (acac) 2 , WO 2 Cl 2 , and VO(acac) 2 in the reduction of sulfoxides with PhSiH 3 or HBcat. The results obtained showed that the catalyst systems PhSiH 3 /HReO 4 (5 mol %) and HBcat/HReO 4 (5 mol %) are highly efficient for