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Reduction of pyracylene by alkali metals: Mechanism and formation of aggregates

โœ Scribed by Gil Zilber; Vladimir Rozenshtein; Ari Ayalon; Haim Levanon; Mordecal Rabinovitz; Lawrence T. Scott; Hope B. Warren; Gaby Persy; Jakob Wirz

Book ID
114996546
Publisher
Springer Netherlands
Year
1996
Tongue
English
Weight
657 KB
Volume
22
Category
Article
ISSN
0922-6168

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๐Ÿ“œ SIMILAR VOLUMES

Stereochemistry of reduction of cyclic k
Stereochemistry of reduction of cyclic ketones by alkali metals and by sodium dithionite.
โœ Graziano Castaldi; Giulio Perdoncin; Claudio Giordano; Francesco Minisci ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 243 KB

Surmary: An opposite stereoselectivity is observed in the r&cticn of 3d-hydroxy-5j%7-oxo-cholaic acid by alkali notals and by sodiun dithicnite, ccntraty to the results reported' with other cyclic or bicyclic ketones. An electrartrznsfer mechanism follmed by coupling of the ketyl radical with SOI is