EPR study of the reduction and cleavage of triphenylphosphine by alkali metals
✍ Scribed by R. Nasirov; S. P. Solodovnikov; M. I. Kabachnik
- Book ID
- 112816951
- Publisher
- Springer
- Year
- 1976
- Tongue
- English
- Weight
- 161 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1573-9171
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📜 SIMILAR VOLUMES
## Abstract The reduction of thiophosphorus acid chlorides with alkali metals (Na, K) in liq. NH~3~/THF solution, potassium anthracenide, and potassium naphthalenide was investigated. It was found that these types of phosphorus compounds easily undergo reduction to >PS^−^ anions. It was also demon
## Abstract The reductive cleavage of phenylalkylphosphines Ph~2~PR, PhPR~2~ (R = Bu, iPr) with Na/NH~3~ is unselective: both phenyl and alkyl groups can be cleaved and Birch reduction may occur. Reaction of Ph~2~tBuP gives a high yield of diphenylphosphide. Polar groups (CO~2~Na, SO~3~,Na) at the