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Reduction of organic azides to amines using reusable Fe3O4 nanoparticles in aqueous medium

โœ Scribed by Pagoti, Sreenivasarao; Surana, Subham; Chauhan, Ajay; Parasar, Bibudha; Dash, Jyotirmayee

Book ID
118157218
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
502 KB
Volume
3
Category
Article
ISSN
2044-4753

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## Abstract Azides were reduced to the corresponding amines by two new metal/Lewis acid systems in aqueous EtOH with yields ranging from 80% to 95%. The new reduction systems were Fe/AlCl~3~ยท6H~2~O or Fe/BiCl~3~ system in H~2~O/ethanol (2:1, __V__:__V__) at room temperature. Fifteen azides with dif