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Reduction of Ketimines by Samarium(II) Complexes. Isolation and Structural Characterization of Samarium(III) η 1 -Amine/ η 1 -Ketimido and η 2 -Ketimine Complexes

✍ Scribed by Hou, Zhaomin; Yoda, Chikako; Koizumi, Take-aki; Nishiura, Masayoshi; Wakatsuki, Yasuo; Fukuzawa, Shin-ichi; Takats, Josef


Book ID
125951730
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
156 KB
Volume
22
Category
Article
ISSN
0276-7333

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μ-η1:η1-N,N'-Imidazolidine-Bridged Dicop
✍ Manindranath Bera; Wing Tak Wong; Guillem Aromí; Debashis Ray 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 1 views

## Abstract The copper coordination chemistry of a new imidazolidine‐based doubly bridging μ‐bis(tetradentate) ligand, H~3~mhbai is studied. A new family of pentacoordinate dinuclear complexes of formula [Cu^II^~2~(‐mhbai)(‐X)]·2 H~2~O (1–4) [X = OAc, NO~3~, Cl, S~2~COMe], where H~3~mhbai stands fo