μ-η1:η1-N,N′-Imidazolidine-Bridged Dicopper(II/III) Complexes of a New Dinucleating μ-Bis(tetradentate) Schiff Base Ligand: Synthesis, Structural Characterization, 1H NMR Spectroscopy, and Magnetic Coupling

μ-η1:η1-N,N'-Imidazolidine-Bridged Dicop

μ-η1:η1-N,N'-Imidazolidine-Bridged Dicopper(II/III) Complexes of a New Dinucleating μ-Bis(tetradentate) Schiff Base Ligand: Synthesis, Structural Characterization, 1H NMR Spectroscopy, and Magnetic Coupling

✍ Manindranath Bera; Wing Tak Wong; Guillem Aromí; Debashis Ray 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB

## Abstract The copper coordination chemistry of a new imidazolidine‐based doubly bridging μ‐bis(tetradentate) ligand, H~3~mhbai is studied. A new family of pentacoordinate dinuclear complexes of formula [Cu^II^~2~(‐mhbai)(‐X)]·2 H~2~O (1–4) [X = OAc, NO~3~, Cl, S~2~COMe], where H~3~mhbai stands fo