Synthetic and Structural Studies of Butterfly Fe/S/P Cluster Complexes Related to the Active Site of [FeFe]-Hydrogenases. Proton Reduction to H 2 Catalyzed by (η 1 -Ph 2 PS-η 1 ) 2 Fe 2 (CO) 6

Electrochemical Insights into the Mechan

Electrochemical Insights into the Mechanisms of Proton Reduction by [Fe2(CO)6{μ-SCH2N(R)CH2S}] Complexes Related to the [2Fe]H Subsite of [FeFe]Hydrogenase

✍ Jean-François Capon; Salah Ezzaher; Frédéric Gloaguen; François Y. Pétillon; Phi 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 500 KB 👁 1 views

## Abstract Electrochemical investigations on a structural analogue of the [2Fe]~H~ subsite of [FeFe]H~2~ases, namely, [Fe~2~(CO)~6~{μ‐SCH~2~N(CH~2~CH~2~‐ OCH~3~)CH~2~S}] (1), were conducted in MeCN/NBu~4~PF~6~ in the presence of HBF~4~/Et~2~O or HOTs. Two different catalytic proton reduction proce