๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Reduction of aralkyl halides with diborane in nitromethane

โœ Scribed by Shoichi Matsumura; Niichiro Tokura

Book ID
104239020
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
151 KB
Volume
10
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

In continuation of the work in a previously published paper, 1 we wish to 2 report the effective reduction of aralkyl halides with diborane in nitromethane.

๐Ÿ“œ SIMILAR VOLUMES

Preparation of triethylamine-borane or p
Preparation of triethylamine-borane or pyridine-borane in liquid sulfur dioxide and reduction of aralkyl halides with base-borane complex in liquid sulfur dioxide or in nitromethane
โœ Shoichi Matsumura; Niichiro Tokura ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 167 KB

This reaction was very fast, so it is necessary to moderate the reaction velocity by adding ether to the system. \*\* Pyridine-borane was used.

Diborane reduction of carboxyl groups in
Diborane reduction of carboxyl groups in carbohydrates
โœ F. Smith; A.M. Stephen ๐Ÿ“‚ Article ๐Ÿ“… 1960 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 337 KB

ESTER and lactone groups in carbohydrate compounds may be reduced by complex metal hydrides in aqueous solution 1,2 or in dry ether-type solvents.3g4y5 Reduction of carboxyl groups may also be effected by lithium aluminum hydride6 and related metal hydrides, but the method is limited to carboxylic a

Electrochemical reduction of unsaturated
Electrochemical reduction of unsaturated nitriles in acetonitrile and nitromethane
โœ James Y. Becker; Theodore A. Koch ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 276 KB

The electrochemical reduction of five conjugated and non-conjugated nitriles, CH3CH--CHCN (la, trans/cis = 62/38%); CH3CH2CH--CHCN (lb, cis); CH3CH~CHCH2CN (lc, trans), CH3CH~C(CH3)CN (ld) and CH2~CHCH(CH3)CN (le) have been investigated in acetonitrile, and of two derivatives, la and CHz--C(CH3)CN (

The mechanism of the reduction of ฮฑ,ฮฒ-un
The mechanism of the reduction of ฮฑ,ฮฒ-unsaturated (steroid) ketones with diborane
โœ Ian Midgley; Carl Djerassi ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 130 KB

Caglioti and coworkers have shown that certain a&unsaturated ketones react with excess diborane, and after hydrolysis of the organoborane intermediate with acetic anhydride, good yields of an alkene are obtained. 192 The reaction undoubtedly follows the course depicted in the Scheme: Scheme