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Redox Isomerism in the Lanthanide Complex [(dpp-Bian)Yb(DME)(μ-Br)] 2 (dpp-Bian = 1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene) †

✍ Scribed by Fedushkin, Igor L.; Maslova, Olga V.; Baranov, Eugeny V.; Shavyrin, Andrei S.


Book ID
120927458
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
692 KB
Volume
48
Category
Article
ISSN
0020-1669

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✍ Igor L. Fedushkin; Alexandra A. Skatova; Georgii K. Fukin; Markus Hummert; Herbe 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 140 KB

## Abstract The enolates [(dpp‐bian)(H)]Mg[OC(=CHPh)CH~2~Ph](THF)~2~ (6), [(dpp‐bian)(H)]Mg[OC(=CPh~2~)CH~3~](THF)~2~ (7) and [(dpp‐bian)(H)]Mg(camphor)(py)~2~ (8) were prepared by treating (dpp‐bian)Mg(THF)~3~ (1) with equimolar amounts of dibenzyl ketone, 1,1‐diphenylacetone and camphor, respecti