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Reactions of (dpp-BIAN)Mg(thf)3complex (dpp-BIAN is 1,2-bis{(2,6-diisopropylphenyl)imino}acenaphthene) with halogen-containing reagents

โœ Scribed by I. L. Fedushkin; A. A. Skatova; A. N. Lukoyanov; V. A. Chudakova; S. Dechert; M. Hummert; H. Schumann


Book ID
106519540
Publisher
Springer
Year
2004
Tongue
English
Weight
719 KB
Volume
53
Category
Article
ISSN
1573-9171

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## Abstract The enolates [(dppโ€bian)(H)]Mg[OC(=CHPh)CH~2~Ph](THF)~2~ (6), [(dppโ€bian)(H)]Mg[OC(=CPh~2~)CH~3~](THF)~2~ (7) and [(dppโ€bian)(H)]Mg(camphor)(py)~2~ (8) were prepared by treating (dppโ€bian)Mg(THF)~3~ (1) with equimolar amounts of dibenzyl ketone, 1,1โ€diphenylacetone and camphor, respecti

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