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Synthesis, Molecular Structure and DFT Study of [(dpp-bian)GaM(Et2O)3] (M=Li, Na; dpp-bian=1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene)

✍ Scribed by Igor L. Fedushkin; Anton N. Lukoyanov; Georgy K. Fukin; Sergey Yu. Ketkov; Markus Hummert; Herbert Schumann


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
268 KB
Volume
14
Category
Article
ISSN
0947-6539

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## Abstract The enolates [(dpp‐bian)(H)]Mg[OC(=CHPh)CH~2~Ph](THF)~2~ (6), [(dpp‐bian)(H)]Mg[OC(=CPh~2~)CH~3~](THF)~2~ (7) and [(dpp‐bian)(H)]Mg(camphor)(py)~2~ (8) were prepared by treating (dpp‐bian)Mg(THF)~3~ (1) with equimolar amounts of dibenzyl ketone, 1,1‐diphenylacetone and camphor, respecti