## Abstract __p__โFluorophenyl phosphonic oxide reacts with different type of alcohols, and with tertiary alcohols in the presence of a tertiary base, to yield the corresponding __p__โfluorophenyl phosphonic monoesters.
Recherches sur la formation et la transformation des esters XXXVIII. Sur la phosphonylation de divers types d'alcools
โ Scribed by Emile Cherbuliez; Br. Baehler; H. Probst; J. Rabinowitz
- Publisher
- John Wiley and Sons
- Year
- 1962
- Tongue
- German
- Weight
- 342 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
โฆ Synopsis
Abstract
The preparation of the phenylphosphonic monoesters of tribromoethanol, propargyl alcohol, glycerol, choline, menthol, and borneol is described.
๐ SIMILAR VOLUMES
## Abstract Threated with phenylphosphonic oxide in the presence of triethylamine, primary aliphatic terpenic alcohols yield the corresponding phenylphosphonic monoesters.
Bestimmung der H,O,-Konzentration zu verschiedenen Zeiten wie bisher [2] mit Titanylsulfat. Die in Fig. 4 aufgetragene H,Oa-Konzentration nach 20 Std. istda deren Zunahmc hier noch etwa zeitproportional ist (s. Fig. 2 und 3 )ein Majs fur die Geschwiudigkeit der Autoxydationsreaktion. SUMMARY The ef
Les monoesters des acides phosphoniques sont peu connus. On en trouve quelques exemplcs dans la litteratwe, mais leur synthkse se fait par des mCthodes tout a fait particuliPrcs. Ainsi, par action de C,H,PCl, sur C,H,OH on obtient l'ester monokthyl-phenylphosphonique2) ; C,H,POCl, trait6 par une mol
Treated with a primary or secondary alcohol, phenylphosphonic oxide (C~6~H~5~PO~2~)~n~ gives the corresponding phosphonic monoesters in very good yield.
Phenylphosphonic oxide reacts with halogenated alcohols to give the corresponding halogenoalkyl phenylphosphonic monoesters in very good yields.