## Abstract The preparation of the phenylphosphonic monoesters of tribromoethanol, propargyl alcohol, glycerol, choline, menthol, and borneol is described.
Recherches sur la formation et la transformation des esters XXXVII. Sur la phosphonylation de quelques alcools terpéniques primaires
✍ Scribed by Emile Cherbuliez; G. Weber; A. Yazgi; J. Rabinowitz
- Publisher
- John Wiley and Sons
- Year
- 1962
- Tongue
- German
- Weight
- 274 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Threated with phenylphosphonic oxide in the presence of triethylamine, primary aliphatic terpenic alcohols yield the corresponding phenylphosphonic monoesters.
📜 SIMILAR VOLUMES
## Abstract The phosphorylation of some amino‐alcohols by polyphosphoric acid under reduced pressure is described.
Les monoesters des acides phosphoniques sont peu connus. On en trouve quelques exemplcs dans la litteratwe, mais leur synthkse se fait par des mCthodes tout a fait particuliPrcs. Ainsi, par action de C,H,PCl, sur C,H,OH on obtient l'ester monokthyl-phenylphosphonique2) ; C,H,POCl, trait6 par une mol
Treated with a primary or secondary alcohol, phenylphosphonic oxide (C~6~H~5~PO~2~)~n~ gives the corresponding phosphonic monoesters in very good yield.
Phenylphosphonic oxide reacts with halogenated alcohols to give the corresponding halogenoalkyl phenylphosphonic monoesters in very good yields.
## Abstract Carboxy‐alkyl phenylphosphonic monoesters are obtained very easily by selective hydrolysis (in alcaline medium) of the corresponding carbamido‐ or cyano‐alkyl phenylphosphonic monoesters and sometimes of the corresponding carbethoxy‐alkyl phenylphosphonic monoesters and sometimes of the