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Recent Progress in Aerobic Oxidation of Hydrocarbons by N-Hydroxyimides

โœ Scribed by Yasutaka Ishii; Satoshi Sakaguchi


Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES


Oxyfunctionalization of hydrocarbons by
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The oxidation of hydrocarbons such as adamantane, cyclohexane, tetraline and indane has been investigated using the oxygenr3-methylbutanal system in the presence and in the absence of metal catalyst. The reactivity order reflects the facility of hydrogen abstraction from the substrate. q 1998 Elsevi

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Alkylbenzenes are selectively functionalised to the corresponding acetates by nitric aerobic oxidation catalysed by N-hydroxyphthalimide and iodine. With cyclohexane the oxidation leads to a mixture of cyclohexyl acetate and trans-2-iodocyclohexyl acetate. The mechanism is discussed.

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Tertiary benzylamides are easily and selectively converted into aldehydes by molecular oxygen; the reaction is catalysed by N-hydroxyamides and Co(II).